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The nicotine from the cigarettes will be present in both the urine sample and the blood (actually it is cotinine at that point but lets not get into the science)

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Clinical appearance of lesions associated with the use of loose and portion-bag packed Swedish moist snuff: a comparative study

So it's really the coffee-cigarette association that is dangerous, since caffeine would increase the tobacco dependence

The quick and simple answer is that vaping can save you an estimated 92% if you smoke a pack per day